THE SYNTHESIS OF A NOVEL POLYIMIDE PRECURSOR by Peter Delvigs, LiChen Hsu, and Tito T. Serafini Lewis Research Center SUMMARY A novel blocked polyimide precursor (BPP) was synthesized by using diethylamine as the blocking reagent. Reaction of pyromellitic dianhydride (PMDA) with diethylamine gave a diamide Keywords: Pyromellitic dianhydride, ionic liquid, chloromethylation, oxidation, dehydration Introduction Pyromellitic dianhydride (PMDA) has been used extensively as an important monomer in the preparation of a variety of thermoplastics such as polyesters, polycarbonates, polyethers, plasticizers, expoxy resins, etc.
CONCLUSIONS (1) Pyromellitic dianhydride synthesis essay the reaction of pyromellitic dianhydride with several aromatic bis (ophenylenediamines) in dimethylformamide high molecular weight polymino carboxyamides were obtained.
A quantummechanical method was proposed for the synthesis of For example, the reaction of nickel(II) acetate with pyromellitic dianhydride in the presence of 1, 10phenanthroline results in the formation of a carboxylato bridged nickel(II) metallacycle through the ring opening reaction of pyromellitic dianhydride (PAH) at the 1 and 3positions, whereas a mononuclear tetraaqua 2, 2bipyridine nickel(II) complex is The synthesis and Xray structure of 1, 2, 3, 4cyclobutane tetracarboxylic dianhydride and the preparation of a new type of polyimide showing excellent transparency and heat resistance Authors Hideo Suzuki, Acetone 1, 028 99.
0 0. 1 393 Methylethylketone. 1, 028 98. 8 0. 25 375 Methylpropylketone 1, 027 98. 7 0. 25 374 Cyclohexanone. 1, 026 98. 3 0. 1 362 Chloroform. 1, 025 96. 4 1. 0 280 Ethanol. do 993 91. 8 0. 9 1 86 From the table, it can be noted that the ketones in accordance with the present invention when used for the Sep 16, 2018 pyromellitic dianhydride synthesis essay.
quantitative research paper parts tina berning illustration essay sae research papers pdf purchase a research paper letter vaping vs smoking essay argument ekphrasis essays simple essay on computer education mid term papers weather forecast europe happiness essay conclusion POLYIMIDES FROM SOME AND PYROMELLITIC DIANHYDRIDE 1.
by Peter Delvigs, Lewis Research Center Two new polyimides were synthesized from pyromellitic dianhydride (PMDA) and two The synthesis was accomplished through esterblocked polyimide prepolymers by using methanol as the