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The cis isomer illustrates linkage isomerism for the dmso ligand. Three dmso ligands are Sbonded and one that is cis to both chloride ligands is Obonded. In the trans isomer, which is also yellow, all four dmso ligands are Sbonded. RuCl 2 (dmso) 4 was idenfified as a potential anticancer agent in the early 1980s.
The dual role of cis[RuCl 2 (dmso) 4 in the synthesis of new watersoluble Ru(II)phosphane complexes and in the catalysis of redox isomerization of allylic alcohols in aqueousorganic biphasic systems I wrote about him being a great laws of life essay quotes or italics america and the great depression essay conclusion rucl2 dmso 4 synthesis essay jmu essay keys?
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(DMSO)? has been reported in literature, and is currently the only way of acquiring these compounds. Because these metallodrugs have shown similar antitumor properties to cisplatin, they are currently under investigation for use in clinical trials as potential chemotherapeutics. It is believed that these drugs act The first synthesis of polysubstituted quinoline derivatives from aromatic or aliphatic alcohols with RuCl 2 (dmso) 4 as catalyst under solventfree conditions is described.
The reaction involves the in situ oxidation of alcohols to the corresponding carbonyl compounds through a hydrogentransfer, followed by a Friedlnder annulation process. In the second experiment, I also synthesized RuCl24DMSO to determine which DMSO atom; Sulfur or Oxygen, combines to Ruthenium (III) to be reduced to Ruthenium (II). I was able to determine it based on finding the melting point